Abstract
Polycrystalline diamonds are harder and tougher than single-crystal diamonds and are therefore valuable for cutting and polishing other hard materials, but naturally occurring polycrystalline diamond is unusual and its production is slow. Here we describe the rapid synthesis of pure sintered polycrystalline diamond by direct conversion of graphite under static high pressure and temperature. Surprisingly, this synthesized diamond is ultrahard and so could be useful in the manufacture of scientific and industrial tools.
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References
Kawai, N. & Endo, S. Rev. Sci. Instr. 41, 1178–1181 (1970).
Bundy F. P., Hall, H. T., Strong, H. M. & Wentorf, R. H. Nature 176, 51–55 (1955).
Sumiya, H., Toda, N. & Sato, S. Diamond Rel. Mater. 6, 1841–1846 (1997).
Brookes, C. A. & Brookes, E. J. Diamond Rel. Mater. 1, 13–17 (1991).
Bundy, F. P. J. Chem. Phys. 38, 631–643 (1963).
Naka, S., Horii, K., Takeda, Y. & Hanawa, T. Nature 259, 38–39 (1976).
DeCarli, P. S. Mater. Res. Soc. Symp. Proc. 383, 21–31 (1995).
Yusa, H. et al. Appl. Phys. Lett. 72, 1843–1845 (1998).
Hall, H. T. Science 169, 868–869 (1970).
Krauss, A. R. et al. Diamond Rel. Mater. 10, 1952–1961 (2001).
Katzman, H. & Libby, W. F. Science 172, 1132–1133 (1971).
Akaishi, M. & Yamaoka, S. Mater. Sci. Eng. A209, 54–59 (1996).
De, S., Heaney, P. J., Vicenzi, E. P. & Wang, J. Earth Planet. Sci. Lett. 185, 315–330 (2001).
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Irifune, T., Kurio, A., Sakamoto, S. et al. Ultrahard polycrystalline diamond from graphite. Nature 421, 599–600 (2003). https://doi.org/10.1038/421599b
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DOI: https://doi.org/10.1038/421599b
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