Abstract
Strong chemical activity and extreme instability in ambient conditions characterize carbyne, an infinite sp1 hybridized carbon chain. As a result, much less has been explored about carbyne as compared to other carbon allotropes such as fullerenes, nanotubes and graphene. Although end-capping groups can be used to stabilize carbon chains, length limitations are still a barrier for production, and even more so for application. We report a method for the bulk production of long acetylenic linear carbon chains protected by thin double-walled carbon nanotubes. The synthesis of very long arrangements is confirmed by a combination of transmission electron microscopy, X-ray diffraction and (near-field) resonance Raman spectroscopy. Our results establish a route for the bulk production of exceptionally long and stable chains composed of more than 6,000 carbon atoms, representing an elegant forerunner towards the final goal of carbyne’s bulk production.
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Acknowledgements
This work was supported by the Austrian Science Fund (FWF, NanoBlends I 943–N19). L.S. acknowledges the scholarship supported by the China Scholarship Council. K.S. and Y.N. acknowledge the JST Research Acceleration Programme. J.K. and J.C.M. acknowledge financial support by the European Research Council Starting Grant No. 336453-PICOMAT. J.K. acknowledges FWF for funding through project MA14-009, as well as Vienna Scientific Cluster for computational time, and he also thanks G. Kresse and M. Marsman for their help in DFT calculations. S.C. acknowledges financial support from the Marie Curie Grant FP7-PEOPLE-2013-IEF project ID 628876. A.R. acknowledges financial support by the European Research Council Advanced Grant DYNamo (ERC-2010-AdG-267374), POCAONTAS (FP7-PEOPLE-2012-ITN No. 316633), MINECO (FIS2013-46159-C3-1-P), Grupo Consolidado UPV/EHU del Gobierno Vasco (IT578-13), AFOSR Grant No. FA2386-15-1-0006 AOARD 144088, and COST Action MP1306 (EUSpec). Z.J.L. and L.N. acknowledge Swiss National Science Foundation (CR2212-152944). We acknowledge H. Kuzmany for his constructive discussion about the low-temperature Raman spectra of LLCCs@DWCNTs. We thank S. Puchegger from the Faculty Center for Nanostructure Research for support with SEM imaging.
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All authors contributed to this work. L.S. and T.P. designed and supervised the experiments. L.S. prepared the samples. L.S. and P.R. did far-field Raman characterization. K.S. and Y.N. performed HRTEM characterization and simulation. J.K. and J.C.M. did the STEM measurement and simulation. J.K. did the DFT calculations. H.P. did the XRD measurement. M.W., S.C. and A.R. performed the ab initio DFT calculations. Z.J.L. and L.N. performed the near-field Raman spectroscopy of individual LLCCs@DWCNTs. L.S., P.A. and T.P. analysed data and wrote the manuscript and the Supplementary Information. All authors discussed the results and commented on the manuscript at all stages.
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Shi, L., Rohringer, P., Suenaga, K. et al. Confined linear carbon chains as a route to bulk carbyne. Nature Mater 15, 634–639 (2016). https://doi.org/10.1038/nmat4617
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DOI: https://doi.org/10.1038/nmat4617
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