This year marks the 50th anniversary of Baird’s rules of aromaticity — a set of perturbational molecular orbital theory analyses that has garnered considerable attention in the past ten years in light of its many real-world applications in photochemistry.
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References
Baird, N. C. J. Am. Chem. Soc. 94, 4941–4948 (1972).
Slanina, T. et al. J. Am. Chem. Soc. 142, 10942–10954 (2020).
Aihara, J.-I. Bull. Chem. Soc. Jpn. 51, 1788–1792 (1788).
Shukla, D. & Wan, P. J. Am. Chem. Soc. 115, 2990–2991 (1993).
Wan, P. & Krogh, E. J. Chem. Soc. Chem. Commun. 1207–1208 (1985).
Gogonea, V., Schleyer, Pv. R. & Schreiner, P. R. Angew. Chem. Int. Ed. 37, 1945–1948 (1998).
Rosenberg, M. et al. Chem. Rev. 114, 5379–5425 (2014).
Papadakis, R. & Ottosson, H. Chem. Soc. Rev. 44, 6472–6493 (2015).
Karas, L. J., Wu, C.-H. & Wu, J. I. J. Am. Chem. Soc. 143, 17970–17974 (2021).
Mohamed, R. K. et al. J. Am. Chem. Soc. 137, 15441–15450 (2015).
Kim, H. et al. Nat. Commun. 12, 5409 (2021).
Hada, M. et al. J. Am. Chem. Soc. 139, 15792–15800 (2017).
Zhao, Z. et al. Nat. Commun. 10, 2952 (2019).
Sung, Y. M. et al. Nat. Chem. 7, 418–422 (2015).
Chen, D. et al. Commun. Chem. 1, 18 (2018).
Zeng, W. et al. Chem. Sci. 12, 6159–6171 (2021).
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Karas, L.J., Wu, J.I. Baird’s rules at the tipping point. Nat. Chem. 14, 723–725 (2022). https://doi.org/10.1038/s41557-022-00988-z
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DOI: https://doi.org/10.1038/s41557-022-00988-z