Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Prolonged mantle residence of zircon xenocrysts from the western Eger rift

Abstract

Zircon is a common mineral in continental crustal rocks. As it is not easily altered in processes such as erosion or transport, this mineral is often used in the reconstruction of geological processes such as the formation and evolution of the continents. Zircon can also survive under conditions of the Earth’s mantle, and rare cases of zircons crystallizing in the mantle significantly before their entrainment into magma and eruption to the surface have been reported1,2,3. Here we analyse the isotopic and trace element compositions of large zircons of gem quality from the Eger rift, Bohemian massif, and find that they are derived from the mantle. (U–Th)/He analyses suggest that the zircons as well as their host basalts erupted between 29 and 24 million years ago, but fragments from the same xenocrysts reveal U–Pb ages between 51 and 83 million years. We note a lack of older volcanism and of fragments from the lower crust, which suggests that crustal residence time before eruption is negligible and that most rock fragments found in similar basalts from adjacent volcanic fields equilibrated under mantle conditions. We conclude that a specific chemical environment in this part of the Earth’s upper mantle allowed the zircons to remain intact for about 20–60 million years.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Study area and collage of zircon photographs.
Figure 2: Cathodoluminescence images and U–Pb data of fragments from different zircon xenocrysts.
Figure 3: REE patterns measured on four different zircon xenocrysts.

Similar content being viewed by others

References

  1. Visoná, D. et al. Zircon megacrysts from basalts of the Venetian Volcanic Province (NE Italy): U–Pb ages, oxygen isotopes and REE data. Lithos 94, 168–180 (2007).

    Google Scholar 

  2. Kinny, P. D. & Meyer, H. O. A. Zircons from the mantle: A new way to date old diamonds. J. Geol. 102, 475–481 (1994).

    Google Scholar 

  3. Belousova, E. A. et al. Two age populations of zircons from the Timber Creek kimberlites, Northern Territory, as determined by laser-ablation ICP-MS analysis. Aust. J. Earth Sci. 48, 757–765 (2001).

    Google Scholar 

  4. Mezger, K. & Krogstad, E. J. Interpretation of discordant U–Pb ages: An evaluation. J. Metamorphic Geol. 15, 127–140 (1997).

    Google Scholar 

  5. Rubatto, D. & Hermann, J. Zircon behaviour in deeply subducted rocks. Elements 3, 31–35 (2007).

    Google Scholar 

  6. Zartman, R. E. & Richardson, S. H. Evidence from kimberlitic zircon for a decreasing mantle Th/U since the Archean. Chem. Geol. 220, 263–283 (2005).

    Google Scholar 

  7. Belousova, E. A., Griffin, W. L. & Pearson, N. J. Trace element composition and cathodoluminescence properties of southern African kimberlitic zircons. Mineral. Mag. 62, 355–366 (1998).

    Google Scholar 

  8. Griffin, W. L. et al. The Hf isotope composition of cratonic mantle: LAM-MC-ICPMS analyses of zircon megacrysts in kimberlites. Geochim. Cosmochim. Acta 64, 133–147 (2000).

    Google Scholar 

  9. Page, F. Z. et al. Zircons from kimberlite: New insights from oxygen isotopes, trace elements, and Ti in zircon thermometry. Geochim. Cosmochim. Acta 71, 3887–3903 (2007).

    Google Scholar 

  10. Cherniak, D. J. & Watson, E. B. Pb diffusion in zircon. Chem. Geol. 172, 5–24 (2000).

    Google Scholar 

  11. Wilson, M. & Downes, H. in European Lithosphere Dynamics (eds Gee, D. G. & Stephenson, R. A.) 147–166 (Geol. Soc. London, Memoirs 32, 2006).

    Google Scholar 

  12. Ferry, J. M. & Watson, E. B. New thermodynamic models and revised calibrations for the Ti-in-zircon and Ti-in-rutile thermometers. Contrib. Mineral. Petrol. 154, 429–437 (2007).

    Google Scholar 

  13. Ferriss, E. D. A., Essene, E. J. & Becker, U. Computational study of the effect of pressure on the Ti-in-zircon geothermometer. Eur. J. Mineral. 20, 745–755 (2008).

    Google Scholar 

  14. Trail, D. et al. Constraints on Hadean zircon protoliths from oxygen isotopes, Ti- thermometry, and rare earth elements. Geochem. Geophys. Geosyst. 8, 1–22 (2007).

    Google Scholar 

  15. Monteleone, B. D. et al. Late Miocene-Pliocene eclogite facies metamorphism, D’Entrecasteaux Islands, SE Papua New Guinea. J. Metamorph. Geol. 25, 245–265 (2007).

    Google Scholar 

  16. Valley, J. W. in Zircon (eds Hanchar, J. M. & Hoskin, P. W. O.) 343–385 (Rev. Mineral. 53, 2003).

    Google Scholar 

  17. Yuan, H. L. et al. Simultaneous determinations of U–Pb age, Hf isotopes and trace element compositions of zircon by excimer laser-ablation quadrupole and multiple-collector ICP-MS. Chem. Geol. 247, 100–118 (2008).

    Google Scholar 

  18. Ulrych, J., Lloyd, F. E. & Balogh, K. Age relations and geochemical constraints of Cenozoic alkaline volcanic series W Bohemia: A review. GeoLines 15, 168–180 (2003).

    Google Scholar 

  19. Reiners, P. W., Spell, T. L., Nicolescu, S. & Zanetti, K. A. Zircon (U–Th)/He thermochronometry: He diffusion and comparisons with 40Ar/39Ar dating. Geochim. Cosmochim. Acta 68, 1857–1887 (2004).

    Google Scholar 

  20. Haase, K. M. & Renno, A. D. Variation of magma generation and mantle sources during continental rifting observed in Cenozoic lavas from the Eger rift, central Europe. Chem. Geol. 257, 192–202 (2008).

    Google Scholar 

  21. Geissler, W. H., Kämpf, H., Seifert, W. & Dulski, P. Petrological and seismic studies of the lithosphere in the earthquake swarm region Vogtland/NW Bohemia, central Europe. J. Volcanol. Geotherm. Res. 159, 33–69 (2007).

    Google Scholar 

  22. Witt-Eickschen, G. Upper mantle xenoliths from alkali basalts of the Vogelsberg, Germany: Implications for mantle upwelling and metasomatism. Eur. J. Mineral. 5, 361–376 (1993).

    Google Scholar 

  23. Witt-Eickschen, G. & Kramm, J. Mantle upwelling and metasomatism beneath central Europe: Geochemical and isotopic constraints from mantle xenoliths from the Rhön (Germany). J. Petrol. 38, 479–493 (1997).

    Google Scholar 

  24. Plomerová, J. et al. Upper mantle beneath the Eger rift (central Europe): Plume or asthenosphere upwelling? Geophys. J. Int. 169, 675–682 (2007).

    Google Scholar 

  25. Siebel, W. & Chen, F. Zircon Hf isotope perspective on the origin and evolution of granitic rocks from eastern Bavaria, SW Bohemian Massif. Int. J. Earth Sci. 10.1007/s00531-009-0442-4 (2009).

  26. Goes, S., Spakman, W. & Bijwaard, H. A lower mantle source for central European volcanism. Science 286, 1928–1931 (1999).

    Google Scholar 

  27. Schmitt, A., Marks, M. A. W., Nesbor, H. D. & Markl, G. The onset and origin of differentiated Rhine Graben volcanism based on U–Pb ages and oxygen isotopic composition of zircon. Eur. J. Mineral. 19, 849–857 (2007).

    Google Scholar 

  28. Bouvier, A., Vervoort, J. D. & Patchett, P. J. The Lu–Hf and Sm–Nd isotopic composition of CHUR: Constraints from unequilibrated chondrites and implications for the bulk composition of terrestrial planets. Earth Planet. Sci. Lett. 273, 48–57 (2008).

    Google Scholar 

  29. Evans, N. J., Byrne, J. P., Keegan, J. T. & Dotter, L. E. Determination of uranium and thorium in zircon, apatite, and fluorite: Application to laser (U–Th)/He thermochronology. J. Anal. Chem. 60, 1159–1165 (2005).

    Google Scholar 

  30. McDonough, W. F. & Sun, S. S. The composition of the Earth. Chem. Geol. 120, 223–253 (1995).

    Google Scholar 

Download references

Acknowledgements

Y. Hong-Lin, Northwest University, Xi’an, and W. Fang, CAS Beijing, assisted with Lu–Hf measurements, E. Reitter, Tübingen University, with Sm–Nd analyses, N. Evans and B. McDonald, Curtin University of Technology, Perth, with U and Th analyses. Ion microprobe work at UCLA was supported by a grant from the Instrumentation and Facilities Program, NSF. We thank J. C. Harvey (Caltech Pasadena, USA) for revising the English and I. Williams (ANU Canberra, Australia) for his valuable comments on an earlier version of the manuscript.

Author information

Authors and Affiliations

Authors

Contributions

S.M. and S.W. provided the zircons and valuable background information. Experiments were carried out by A.K.S. (oxygen, trace elements), F.C. (Lu–Hf), M.D. ((U–Th)/He), S.E. and W.S. (U–Pb, cathodoluminescence). W.S. designed the study. W.S. and A.K.S. interpreted the data and wrote the paper with substantial contribution made by M.D.

Corresponding author

Correspondence to Wolfgang Siebel.

Supplementary information

Supplementary Information

Supplementary Information (PDF 243 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Siebel, W., Schmitt, A., Danišík, M. et al. Prolonged mantle residence of zircon xenocrysts from the western Eger rift. Nature Geosci 2, 886–890 (2009). https://doi.org/10.1038/ngeo695

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/ngeo695

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing