Abstract
There is ample evidence that organic field-effect transistors have reached a stage where they can be industrialized, analogous to standard metal oxide semiconductor (MOS) transistors. Monocrystalline silicon technology is largely based on complementary MOS (CMOS) structures that use both n-type and p-type transistor channels. This complementary technology has enabled the construction of digital circuits, which operate with a high robustness, low power dissipation and a good noise margin. For the design of efficient organic integrated circuits, there is an urgent need for complementary technology, where both n-type and p-type transistor operation is realized in a single layer, while maintaining the attractiveness of easy solution processing. We demonstrate, by using solution-processed field-effect transistors, that hole transport and electron transport are both generic properties of organic semiconductors. This ambipolar transport is observed in polymers based on interpenetrating networks as well as in narrow bandgap organic semiconductors. We combine the organic ambipolar transistors into functional CMOS-like inverters.
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References
Burroughes, J.H. et al. Light-emitting diodes based on conjugated polymers. Nature 347, 539–541 (1990).
Yu, G., Gao, J., Hummelen, J.C., Wudl, F. & Heeger, A.J. Polymer photovoltaic cells: enhanced efficiencies via a network of internal donor-acceptor heterojunctions. Science 270, 1789–1791 (1995).
Dimitrakopoulos, C.D. & Malenfant, P.R.L. Organic thin film transistors for large area electronics. Adv. Mater. 14, 99–117 (2002).
Crone, B. et al. Large-scale complementary integrated circuits based on organic transistors. Nature 403, 521–523 (2000).
Dodabalapur, A., Katz, H.E., Torsi, L. & Haddon, R.C. Organic heterostructure field-effect transistors. Science 296, 1560–1562 (1995).
Dodabalapur, A., Katz, H.E., Torsi, L. & Haddon, R.C. Organic field-effect bipolar transistors. Appl. Phys. Lett. 68, 1108–1110 (1996).
Huitema, H.E.A. et al. Plastic transistor in active-matrix displays. Nature 414, 599 (2001).
Sirringhaus, H., Tessler, N. & Friend, R.H. Integrated optoelectronic devices based on conjugated polymers. Science 280, 1741–1744 (1998).
Gelinck, G.H., Geuns, T.C.T. & de Leeuw, D.M. High-performance all-polymer integrated circuits. Appl. Phys. Lett. 77, 1487–1489 (2000).
Tada, K., Harada, H. & Yoshino, K. Polymeric bipolar thin-film transistor utilizing conducting polymer containing electron transport dye. Jpn J. Appl. Phys. 35 L944–L946 (1996).
Blom, P.W.M., de Jong, M.J.M. & van Munster, M.G. Electric-field and temperature dependence of the hole mobility in poly(p-phenylene vinylene). Phys. Rev. B. 55, R656–R659 (1997).
Veenstra, S.C., Heeres, A., Hadziioannou, G., Sawatzky, G.A. & Jonkman, H.T. On interface dipole layers between C60 and Ag or Au. Appl. Phys. A, 75, 661–666 (2002).
Sze, S.M. Physics of Semiconductor Devices (Wiley, New York, 1981).
Reisch, H., Wiesler, W., Scherf, U. & Tuytuylkov, N. Poly(indenofluorene) (PIF), a novel low band gap polyhydrocarbon. Macromolecules 29, 8204–8210 (1996).
Neudeck, G.W., Bare, H.F. & Chung, K.Y. Modelling of ambipolar a-Si:H thin-film transistors. IEEE Trans. Electron Dev. 34, 344–350 (1987).
Meijer, E.J. et al. Switch-on voltage in disordered organic field-effect transistors. Appl. Phys. Lett. 80, 3838–3840 (2002).
Vissenberg, M.C.J.M. & Matters, M. Theory of the field-effect mobility in amorphous organic transistors. Phys. Rev. B 57, 12964–12967 (1998).
Detcheverry, C. & Matters, M. Device simulation of all-polymer thin-film transistors. Proc. ESSDERC 328–331 (2000).
van Woudenbergh, T., Blom, P.W.M., Vissenberg, M.C.J.M. & Huiberts, J.N. Temperature dependence of the charge injection in poly-dialkoxy-p-phenylene vinylene. Appl. Phys. Lett. 79, 1697–1699 (2001).
Chung, K.Y., Neudeck, G.W. & Bare, H.F. Analytical modelling of the CMOS-like a-Si:H TFT inverter circuit. IEEE J. Solid-State Circ. 23, 566–572 (1988).
Meijer, E.J. et al. Dopant density determination in disordered organic field-effect transistors. J. Appl. Phys. 93, 4831–4835 (2003).
Herwig, P.T. & Müllen, K. A soluble pentacene precursor: synthesis, solid-state conversion into pentacene and application in a field-effect transistor. Adv. Mater. 11, 480–483 (1999).
Brown, A.R., Jarrett, C.P., de Leeuw, D.M. & Matters, M. Field-effect transistors made from solution-processed organic semiconductors. Synth. Met. 88, 37–55 (1997).
Cormier, R.A. & Gregg, B.A. Synthesis and characterization of liquid crystalline perylene diimides. Chem. Mater. 10, 1309–1319 (1998).
de Leeuw, D.M., Simenon, M.M.J., Brown, A.R. & Einerhand, R.E.F. Stability of n-type doped conducting polymers and consequences for polymeric microelectronic devices. Synth. Met. 87, 53–59 (1997).
Shaheen, S.E. et al. 2.5% efficient organic plastic solar cells. Appl. Phys. Lett. 78, 841–843 (2001).
Acknowledgements
The authors acknowledge Brian Gregg (National Renewable Energy Laboratory, Golden, Colerado, USA) for providing a sample of PPEEB, Jitendra Jadam for the synthesis of the PIF, Eugenio Cantatore (Philips Research) for useful discussions, Henny Herps (Philips Research) for the design of Fig. 1, and also gratefully acknowledge The Dutch science foundation NWO/FOM through the 'Laboratorium zonder muren' project.
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Meijer, E., de Leeuw, D., Setayesh, S. et al. Solution-processed ambipolar organic field-effect transistors and inverters. Nature Mater 2, 678–682 (2003). https://doi.org/10.1038/nmat978
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DOI: https://doi.org/10.1038/nmat978
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