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Showing 1–6 of 6 results
Advanced filters: Author: "Marco Cammarata" Clear advanced filters
  • Localized chemical events such as the breakage of a bond between a protein and a ligand may trigger a global protein conformational change. Here, the authors use an X-ray free-electron laser to track the motion of myoglobin in response to photoinduced ligand release, and observe a picosecond proteinquake.

    • Matteo Levantino
    • Giorgio Schirò
    • Marco Cammarata
    ResearchOpen Access
    Nature Communications
    Volume: 6, P: 1-6
  • Ultrafast nonadiabatic chemical dynamics during molecular photo-transformations remain challenging to describe since electronic/nuclear configurations are coupled. Here the authors use time-resolved X-ray absorption spectroscopy to probe the light-induced spin-state trapping dynamics of [Fe(bpy)3]2+beyond the Born-Oppenheimer approximation.

    • Henrik T. Lemke
    • Kasper S. Kjær
    • Marco Cammarata
    ResearchOpen Access
    Nature Communications
    Volume: 8, P: 1-8
  • Cyanide-bridged CoFe coordination networks exhibit photomagnetism because of coupled charge-transfer and spin transition. Now, femtosecond X-ray and optical absorption spectroscopies have enabled the electronic and structural dynamics of this light-induced process to be disentangled and show that it is the spin transition on the cobalt atom, occurring within ~50 fs, that induces the Fe-to-Co charge-transfer within ~200 fs.

    • Marco Cammarata
    • Serhane Zerdane
    • Eric Collet
    Research
    Nature Chemistry
    Volume: 13, P: 10-14
  • Ultrafast control of materials draws interest. Here, the authors extend X-ray powder diffraction to the femtosecond timescale to follow the photo-induced semiconductor to metal transition in titanium pentaoxide, observing a phase front that moves at the speed of sound and proposing a little explored mechanism.

    • C. Mariette
    • M. Lorenc
    • M. Cammarata
    ResearchOpen Access
    Nature Communications
    Volume: 12, P: 1-11
  • By taking advantage of free-carrier generation in optically transparent media researchers have improved synchronization between optical lasers and free-electron laser pulses. This technique has an optical/X-ray delay with a sub-10 fs r.m.s error.

    • M. Harmand
    • R. Coffee
    • M. Cammarata
    Research
    Nature Photonics
    Volume: 7, P: 215-218