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Showing 1–4 of 4 results
Advanced filters: Author: "S. Inoue" Clear advanced filters

  • The heavy analogues of ynolates or ketenyl anions have not yet been studied. Here the synthesis, isolation and characterization of a sila-ketenyl anion, the silicon analogue of a ketenyl anion, are reported through the reaction of silyl-radical anions with CO.

    • Shiori Fujimori
    • Arseni Kostenko
    • Shigeyoshi Inoue
    Research
    Nature Synthesis
    Volume: 2, P: 688-694

  • Aluminium and silicon, two Earth-abundant, well-understood elements, typically form weak Al–Si bonds. Now, complexes featuring an anionic Al–Si core stabilized by bulky substituents and a Si–Na interaction have been isolated. This Al–Si interaction possesses partial double bond character, which can be increased by sequestration of the sodium counterion.

    • Moritz Ludwig
    • Daniel Franz
    • Shigeyoshi Inoue
    Research
    Nature Chemistry
    Volume: 15, P: 1452-1460

  • Silyl-substituted silicon–carbonyl complexes that are stable at room temperature have been prepared by exposure of highly reactive bis(silyl)silylenes to carbon monoxide. The compounds show structural features and reactivity that are reminiscent of their ubiquitous transition-metal–carbonyl counterparts, including π-backbonding and ligand liberation as well as substitution and functionalization reactions.

    • Dominik Reiter
    • Richard Holzner
    • Shigeyoshi Inoue
    Research
    Nature Chemistry
    Volume: 12, P: 1131-1135

  • The chemistry of carbon monoxide (CO) as a ligand has evolved significantly and transition-metal carbonyl complexes have been widely used as catalysts in many important catalytic processes. Here the authors comment on the recent progress of main-group element carbonyl complexes along with their future prospects.

    • Shiori Fujimori
    • Shigeyoshi Inoue
    Comments & OpinionOpen Access
    Communications Chemistry
    Volume: 3, P: 1-4