The structure and properties of cyclopropane have intrigued chemists for decades, with an increasing demand for methods to functionalize these small carbocycles. This Review provides a summary of transition-metal-catalysed C–C bond formation at cyclopropanes, including cross-coupling with cyclopropyl nucleophiles or electrophiles, C–H functionalization and single-electron cross-coupling strategies.
- Alexis L. Gabbey
- Katerina Scotchburn
- Sophie A. L. Rousseaux