Indium-free quaternary chalcogenide, Cu2ZnSnSe4 (CZTSe), has driven much attention for its potential application in photovoltaics and optoelectronics. High-quality CZTSe nanocrystals (NCs) with thermodynamically metastable wurtzite phase were herein synthesized via a facile, lost-cost and safe-solution method, in which high reaction rate and low surface energy are favorable for the formation of wurtzite structure. The promising application of the as-synthesized NCs in photovoltaics and optoelectronics has been demonstrated by the high-performance hybrid photodetector made from CZTSe NCs and P3HT.
- Jian-Jun Wang
- Jin-Song Hu
- Li-Jun Wan