Abstract
The 2-Gyr-old Chang’e-5 samples are the youngest lunar basaltic regolith returned to Earth and can provide information on the lithological diversity and regolith gardening processes at young mare regions on the Moon over a hitherto unexplored time window. Here we study the lithology and composition of over 3,000 Chang’e-5 regolith particles less than 2 mm in size and identify 7 exotic igneous clasts: a high-Ti vitrophyric fragment, a low-Ti basalt, an olivine-pyroxenite, a magnesian anorthosite, an evolved lithology, a Mg-rich olivine fragment and a pyroclastic glass bead. We associate them with impact-ejected materials from other regions of the Moon, over 50–400 km away from the Chang’e-5 mare unit. In particular, the pyroclastic bead records a volcanic eruption on the Moon with unique chemical composition, suggesting the presence of additional and yet-unrecognized lunar volcanic eruptions. The significantly lower amount of exotic material in the Chang’e-5 samples (~0.2%) with respect to expectations (~10–20%) might indicate that current modelling of impact ejecta needs to be revisited for young lunar geological units.
This is a preview of subscription content, access via your institution
Access options
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
$29.99 / 30 days
cancel any time
Subscribe to this journal
Receive 12 digital issues and online access to articles
$119.00 per year
only $9.92 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
Data availability
The data resulting from this study are provided in the Article and Supporting Information. LROC WAC data and TiO2 abundance (wt%) data were downloaded from the Planetary Data System (https://planetarymaps.usgs.gov/mosaic/Lunar_LRO_LROC-WAC_Mosaic_global_100m_June2013.tif; http://pds.lroc.asu.edu/data/LRO-L-LROC-5-RDR-V1.0/LROLRC_2001/DATA/SDP/WAC_TIO2/).
References
Li, C. et al. Characteristics of the lunar samples returned by the Chang’e-5 mission. Natl Sci. Rev. 9, nwab188 (2022).
Qian, Y. et al. China’s Chang’e-5 landing site: geology, stratigraphy, and provenance of materials. Earth Planet. Sci. Lett. 561, 116855 (2021).
Che, X. et al. Age and composition of young basalts on the Moon, measured from samples returned by Chang’e-5. Science 374, 887–890 (2021).
Li, Q. L. et al. Two-billion-year-old volcanism on the Moon from Chang’e-5 basalts. Nature 600, 54–58 (2021).
Vaniman, D., Dietrich, J., Taylor, G. J. & Heiken, G. in Lunar Sourcebook, A User’s Guide to the Moon 5–26 (1991).
Qian, Y. et al. Copernican‐aged (<200 Ma) impact ejecta at the Chang’e‐5 landing site: statistical evidence from crater morphology, morphometry, and degradation models. Geophys. Res. Lett. 48, e2021GL095341 (2021).
Xie, M., Xiao, Z., Zhang, X. & Xu, A. The provenance of regolith at the Chang’e‐5 candidate landing region. J. Geophys. Res. Planets 125, e2019JE006112 (2020).
Liu, T., Michael, G., Zhu, M. H. & Wünnemann, K. Predicted sources of samples returned from Chang’e-5 landing region. Geophys. Res. Lett. 48, e2021GL092434 (2021).
Papike, J. J., Ryder, G. & Shearer, C. K. in Planetary Materials (ed. Papike, J. J.) Ch. 5 (Mineralogical Society of America, 1998).
Gross, J. & Treiman, A. H. Unique spinel-rich lithology in lunar meteorite ALHA 81005: origin and possible connection to M3 observations of the farside highlands. J. Geophys. Res. Planets 116, E10009 (2011).
Zeng, X. et al. Multiple lithic clasts in lunar breccia Northwest Africa 7948 and implication for the lithologic components of lunar crust. Meteorit. Planet. Sci. 53, 1030–1050 (2018).
Zeng, X. et al. Occurrence and implications of secondary olivine veinlets in lunar highland breccia Northwest Africa 11273. Meteorit. Planet. Sci. 55, 36–55 (2020).
Zeng, X. et al. New evidence for 4.32 Ga ancient silicic volcanism on the Moon. Geophys. Res. Lett. 48, e2021GL092639 (2021).
Tian, H. C. et al. Non-KREEP origin for Chang’e-5 basalts in the Procellarum KREEP Terrane. Nature 600, 59–63 (2021).
Delano, J. W. Pristine lunar glasses: criteria, data, and implications. J. Geophys. Res. Solid Earth 91, 201–213 (1986).
Naney, M. T., Crowl, D. M. & Papike, J. J. The Apollo 16 drill core—statistical analysis of glass chemistry and the characterization of a high alumina–silica poor/HASP/glass. Lunar Planet. Sci. Conf. Proc. 7, 155–184 (1976).
Gaddis, L. R., Staid, M. I., Tyburczy, J. A., Hawke, B. R. & Petro, N. E. Compositional analyses of lunar pyroclastic deposits. Icarus 161, 262–280 (2003).
Gustafson, J. O., Bell, J. F., Gaddis, L. R., Hawke, B. R. & Giguere, T. A. Characterization of previously unidentified lunar pyroclastic deposits using Lunar Reconnaissance Orbiter Camera data. J. Geophys. Res. Planets 117, E00H25 (2012).
Wieczorek, M. A. et al. The constitution and structure of the lunar interior. Rev. Mineral. Geochem. 60, 221–364 (2006).
Neal, C. R. & Taylor, L. A. Petrogenesis of mare basalts: a record of lunar volcanism. Geochim. Cosmochim. Acta 56, 2177–2211 (1992).
Jolliff, B. L., Gillis, J. J., Haskin, L. A., Korotev, R. L. & Wieczorek, M. A. Major lunar crustal terranes: surface expressions and crust‐mantle origins. J. Geophys. Res. Planets 105, 4197–4216 (2000).
Jolliff, B. L. et al. Non-mare silicic volcanism on the lunar farside at Compton–Belkovich. Nat. Geosci. 4, 566–571 (2011).
Lucey, P. G. Mineral maps of the Moon. Geophys. Res. Lett. 31, L08701 (2004).
Korotev, R. L., Zeigler, R. A., Jolliff, B. L., Irvin, A. J. & Bunch, T. E. Compositional and lithological diversity among brecciated lunar meteorites of intermediate iron concentration. Meteorit. Planet. Sci. 44, 1287–1322 (2009).
Russell, S. S., Joy, K. H., Jeffries, T. E., Consolmagno, G. J. & Kearsley, A. Heterogeneity in lunar anorthosite meteorites: implications for the lunar magma ocean model. Philos. Trans. R. Soc. Lond. A 372, 20130241 (2014).
Gross, J. & Joy, K. H. in Encyclopedia of Lunar Science 1–20 (Springer, 2016).
Nielsen, R. L. & Drake, M. J. in Mare Crisium: the View from Luna 24 (eds Merrill, R. B. & Papike, J. J.) 419–428 (Pergamon Press, 1978).
Arai, T., Warren, P. H. & Takeda, H. Four lunar mare meteorites: crystallization trends of pyroxenes and spinels. Meteorit. Planet. Sci. 31, 877–892 (1996).
Robinson, K. L., & Treiman, A. H. Mare basalt fragments in lunar highlands meteorites: connecting measured Ti abundances with orbital remote sensing. In 41st Annual Lunar and Planetary Science Conference 1788.
Warren, P. H., Taylor, G. J. & Keil, K. Regolith breccia Allan Hills A81005: evidence of lunar origin, and petrography of pristine and nonpristine clasts. Geophys. Res. Lett. 10, 779–782 (1983).
Gross, J., Treiman, A. H. & Mercer, C. N. Lunar feldspathic meteorites: constraints on the geology of the lunar highlands, and the origin of the lunar crust. Earth Planet. Sci. Lett. 388, 318–328 (2014).
Korotev, R. L., Jolliff, B. L., Zeigler, R. A., Gillis, J. J. & Haskin, L. A. Feldspathic lunar meteorites and their implications for compositional remote sensing of the lunar surface and the composition of the lunar crust. Geochim. Cosmochim. Acta 67, 4895–4923 (2003).
Zeigler, R. A., Korotev, R. L., Jolliff, B. L., Haskin, L. A. & Floss, C. The geochemistry and provenance of Apollo 16 mafic glasses. Geochim. Cosmochim. Acta 70, 6050–6067 (2006).
Korotev, R. L., Zeigler, R. A. & Floss, C. On the origin of impact glass in the Apollo 16 regolith. Geochim. Cosmochim. Acta 74, 7362–7388 (2010).
Norman, M. D., Adena, K. J. D. & Christy, A. G. Provenance and Pb isotopic ages of lunar volcanic and impact glasses from the Apollo 17 landing site. Aust. J. Earth Sci. 59, 291–306 (2012).
Sato, H., Robinson, M. S., Lawrence, S. J., Denevi, B. W. & Hiesinger, H. Lunar mare TiO2 abundances estimated from UV/VIS reflectance. Icarus 296, 216–238 (2017).
Acknowledgements
The Chang'e-5 samples were allocated by the China National Space Administration. We thank Y. Wen and X. Li for their assistances with FIB/SEM and EPMA measurements. We are grateful to L. Maltagliati for the editorial handling of the manuscript and we also thank S. Simon for their helpful comments and suggestions during peer review. X.L. acknowledges financial support from the B-type Strategic Priority Program of the Chinese Academy of Sciences (No. XDB41000000), National Natural Science Foundation of China (No. 41931077) and Pre-research project on Civil Aerospace Technologies by CNSA (No. D020201). J.L. acknowledges financial support from the B-type Strategic Priority Program of the Chinese Academy of Sciences (No. XDB41000000) and National Natural Science Foundation of China (No. 41941003). X.Z. gratefully acknowledges support from the National Natural Science Foundation of China (No.42103036).
Author information
Authors and Affiliations
Contributions
X.Z. prepared the Chang’e-5 samples, performed the research and prepared the initial manuscript. X.Z., X.L. and J.L. designed the research. All authors participated in the discussion of results, data interpretation and paper editing.
Corresponding authors
Ethics declarations
Competing interests
The authors declare no competing interests.
Peer review
Peer review information
Nature Astronomy thanks Steve Simon and Noah Petro for their contribution to the peer review of this work.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary information
Supplementary Information
Supplementary Figs. 1–10, Tables 1–7 and references
Supplementary Data
Supplementary Datasets 1–7.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Zeng, X., Li, X. & Liu, J. Exotic clasts in Chang’e-5 regolith indicative of unexplored terrane on the Moon. Nat Astron 7, 152–159 (2023). https://doi.org/10.1038/s41550-022-01840-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41550-022-01840-7
This article is cited by
-
Untrackable distal ejecta on planetary surfaces
Nature Communications (2023)