Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Letter
  • Published:

Electron Spin Resonance Spectra of Heated Polynuclear Hydrocarbons

Abstract

FREE radicals, suitable for study by electron spin resonance spectroscopy, can be obtained from diamagnetic molecules in a number of ways, such as by dissolution in acids, by electrolytic reduction, or by exposure to various forms of radiation. Electron spin resonance spectra have recently been reported from heated compounds, both in solution1 and in the pure state2,3. The latter spectra have not, however, been well resolved, and coupling constants were not reported.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Lunazzi, L., MacCagnani, G., Mangini, A., and Pedulli, G., Tetrahedron Lett., No. 46, 5807 (1966).

  2. Janzen, E. G., J. Amer. Chem. Soc., 87, 3531 (1965).

    Article  CAS  Google Scholar 

  3. Berlin, A. A., Vonsyatskii, V. A., and Lyubchenko, L. S., Izv. Akad. Nauk. S.S.S.R., No. 7, 1184 (1964).

  4. Ayscough, P., McCann, A., and Wilson, R., Proc. Chem. Soc., 16 (1961), and references cited there.

  5. Fritsch, J. M., Layloff, T. P., and Adams, R. N., J. Amer. Chem. Soc., 87, 1724 (1965); compare also Forbes, W. F., and Sullivan, P. D., Canad. J. Chem., 44, 1501 (1966).

    Article  CAS  Google Scholar 

  6. Coulson, C. A., and Streitwieser, jun., A., Dictionary of II Electron Calculations, 133 (W. H. Freeman and Co., San Francisco, 1965).

    Google Scholar 

  7. Wynder, E. L., Wright, G. F., and Lam, J., Cancer, 11, 1140 (1958).

    Article  CAS  Google Scholar 

  8. Smoking and Health, PHS Publication 1103 (U.S. Dept. of Health, Education and Welfare, 1964).

  9. Ingram, D. J. E., Acta Med. Scand., 170, 43 (1961).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

FORBES, W., ROBINSON, J. Electron Spin Resonance Spectra of Heated Polynuclear Hydrocarbons. Nature 214, 80–81 (1967). https://doi.org/10.1038/214080a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/214080a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing